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Silicon Interfacial Passivation Layer Chemistry for High-k/InP Interfaces.

Identifieur interne : 000054 ( Main/Exploration ); précédent : 000053; suivant : 000055

Silicon Interfacial Passivation Layer Chemistry for High-k/InP Interfaces.

Auteurs : RBID : pubmed:24750024

Abstract

The interfacial chemistry of thin (1 nm) silicon (Si) interfacial passivation layers (IPLs) deposited on acid-etched and native oxide InP(100) samples prior to atomic layer deposition (ALD) is investigated. The phosphorus oxides are scavenged completely from the acid-etched samples but not completely from the native oxide samples. Aluminum silicate and hafnium silicate are possibly generated upon ALD and following annealing. The thermal stability of a high-k/Si/InP (acid-etched) stack are also studied by in situ annealing to 400 and 500 °C under ultrahigh vacuum, and the aluminum oxide/Si/InP stack is the most thermally stable. An indium out-diffusion to the sample surface is observed through the Si IPL and the high-k dielectric, which may form volatile species and evaporate from the sample surface.

DOI: 10.1021/am500752u
PubMed: 24750024

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Le document en format XML

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<nlm:affiliation>Department of Materials Science and Engineering, University of Texas at Dallas , Richardson, Texas 75080, United States.</nlm:affiliation>
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<name sortKey="Brennan, Barry" uniqKey="Brennan B">Barry Brennan</name>
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<name sortKey="Zhernokletov, Dmitry" uniqKey="Zhernokletov D">Dmitry Zhernokletov</name>
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<name sortKey="Hinkle, Christopher L" uniqKey="Hinkle C">Christopher L Hinkle</name>
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<name sortKey="Kim, Jiyoung" uniqKey="Kim J">Jiyoung Kim</name>
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<name sortKey="Chabal, Yves J" uniqKey="Chabal Y">Yves J Chabal</name>
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<div type="abstract" xml:lang="en">The interfacial chemistry of thin (1 nm) silicon (Si) interfacial passivation layers (IPLs) deposited on acid-etched and native oxide InP(100) samples prior to atomic layer deposition (ALD) is investigated. The phosphorus oxides are scavenged completely from the acid-etched samples but not completely from the native oxide samples. Aluminum silicate and hafnium silicate are possibly generated upon ALD and following annealing. The thermal stability of a high-k/Si/InP (acid-etched) stack are also studied by in situ annealing to 400 and 500 °C under ultrahigh vacuum, and the aluminum oxide/Si/InP stack is the most thermally stable. An indium out-diffusion to the sample surface is observed through the Si IPL and the high-k dielectric, which may form volatile species and evaporate from the sample surface.</div>
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